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Organic-Inorganic Hybrid Materials: Crystal Growth and XRD Analysis of [(C38H30N8)2•CoCl4] and [(CH3NH3)2•CoCl4]

Received: 7 October 2022     Accepted: 24 October 2022     Published: 30 October 2022
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Abstract

Two tetrachloridocobaltate (II) hybrid compounds were isolated and structurally characterized by single crystal X-ray crystallography. The compound [(C38H30N8)2•CoCl4] (1), crystallizes in the monoclinic space group P21/c with Z = 4, a = 12.0894(7) Å, b = 15.1839(8) Å, c = 19.8015(11) Å, β = 90.786(2)° and V = 3634.5(3) Å3. Compound [(CH3NH3)2•CoCl4] (2), crystallizes in the monoclinic space group P21/c with Z = 4, a = 7.6385(5) Å, b = 12.6684(8) Å, c = 10.8730(6) Å, β = 96.540(2)° and V = 1045.31(11) Å3. The compound 1 consists of 2,3,5-triphenyltetrazolium cations and tetrachloridocobaltate (II) ions connected through weak C-H•••Cl hydrogen bonds affording a 3D structure. Additional π•••π interactions consolidate the stability and the compactness of the 3D framework. The tetrazolium (C1N1N2N3N4) ring forms dihedral angles of 85.04(11), 49.37(11) and 27.85(11)° with the planes of the benzene rings of the substituent groups while the tetrazolium (C20N5N6N7N8) ring forms dihedral angles of 52.92(11), 47.37(11) and 9.97(11)° with the planes of the benzene rings of the substituent groups. The compound 2 is composed of methylammonium cations and tetrachloridocobaltate (II) dianions connected by extended N-H•••Cl hydrogen bonding patterns giving rise to a 3D structure. The methylammonium cations adopt a general position and are not exceptional. In both structures, the Co centre within the dianion is bonded to four chloride ligands and adopts a distorted tetrahedral geometry. The extensive hydrogen bonding patterns within compound 2 describe R22(4), R34(10), R44(12), R55(14), R46(14), R56(16) and R66(18) rings whereas 1, through the weak C-H•••Cl hydrogen bond patterns, generates mainly R21(4) rings and other hydrogen bonds of D type.

Published in Advances in Materials (Volume 11, Issue 4)
DOI 10.11648/j.am.20221104.12
Page(s) 85-93
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2022. Published by Science Publishing Group

Keywords

2,3,5-Triphenyltetrazolium, Methylammonium, Cobalt (II), Single Crystal X-ray Crystallography, 3D Structure

References
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    Mouhamadou Birame Diop, Modou Sarr, Mouhamadou Sembene Boye, Sérigne Cissé, Libasse Diop, et al. (2022). Organic-Inorganic Hybrid Materials: Crystal Growth and XRD Analysis of [(C38H30N8)2•CoCl4] and [(CH3NH3)2•CoCl4]. Advances in Materials, 11(4), 85-93. https://doi.org/10.11648/j.am.20221104.12

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    Mouhamadou Birame Diop; Modou Sarr; Mouhamadou Sembene Boye; Sérigne Cissé; Libasse Diop, et al. Organic-Inorganic Hybrid Materials: Crystal Growth and XRD Analysis of [(C38H30N8)2•CoCl4] and [(CH3NH3)2•CoCl4]. Adv. Mater. 2022, 11(4), 85-93. doi: 10.11648/j.am.20221104.12

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    Mouhamadou Birame Diop, Modou Sarr, Mouhamadou Sembene Boye, Sérigne Cissé, Libasse Diop, et al. Organic-Inorganic Hybrid Materials: Crystal Growth and XRD Analysis of [(C38H30N8)2•CoCl4] and [(CH3NH3)2•CoCl4]. Adv Mater. 2022;11(4):85-93. doi: 10.11648/j.am.20221104.12

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  • @article{10.11648/j.am.20221104.12,
      author = {Mouhamadou Birame Diop and Modou Sarr and Mouhamadou Sembene Boye and Sérigne Cissé and Libasse Diop and Allen G. Oliver and David Renald},
      title = {Organic-Inorganic Hybrid Materials: Crystal Growth and XRD Analysis of [(C38H30N8)2•CoCl4] and [(CH3NH3)2•CoCl4]},
      journal = {Advances in Materials},
      volume = {11},
      number = {4},
      pages = {85-93},
      doi = {10.11648/j.am.20221104.12},
      url = {https://doi.org/10.11648/j.am.20221104.12},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.am.20221104.12},
      abstract = {Two tetrachloridocobaltate (II) hybrid compounds were isolated and structurally characterized by single crystal X-ray crystallography. The compound [(C38H30N8)2•CoCl4] (1), crystallizes in the monoclinic space group P21/c with Z = 4, a = 12.0894(7) Å, b = 15.1839(8) Å, c = 19.8015(11) Å, β = 90.786(2)° and V = 3634.5(3) Å3. Compound [(CH3NH3)2•CoCl4] (2), crystallizes in the monoclinic space group P21/c with Z = 4, a = 7.6385(5) Å, b = 12.6684(8) Å, c = 10.8730(6) Å, β = 96.540(2)° and V = 1045.31(11) Å3. The compound 1 consists of 2,3,5-triphenyltetrazolium cations and tetrachloridocobaltate (II) ions connected through weak C-H•••Cl hydrogen bonds affording a 3D structure. Additional π•••π interactions consolidate the stability and the compactness of the 3D framework. The tetrazolium (C1N1N2N3N4) ring forms dihedral angles of 85.04(11), 49.37(11) and 27.85(11)° with the planes of the benzene rings of the substituent groups while the tetrazolium (C20N5N6N7N8) ring forms dihedral angles of 52.92(11), 47.37(11) and 9.97(11)° with the planes of the benzene rings of the substituent groups. The compound 2 is composed of methylammonium cations and tetrachloridocobaltate (II) dianions connected by extended N-H•••Cl hydrogen bonding patterns giving rise to a 3D structure. The methylammonium cations adopt a general position and are not exceptional. In both structures, the Co centre within the dianion is bonded to four chloride ligands and adopts a distorted tetrahedral geometry. The extensive hydrogen bonding patterns within compound 2 describe R22(4), R34(10), R44(12), R55(14), R46(14), R56(16) and R66(18) rings whereas 1, through the weak C-H•••Cl hydrogen bond patterns, generates mainly R21(4) rings and other hydrogen bonds of D type.},
     year = {2022}
    }
    

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  • TY  - JOUR
    T1  - Organic-Inorganic Hybrid Materials: Crystal Growth and XRD Analysis of [(C38H30N8)2•CoCl4] and [(CH3NH3)2•CoCl4]
    AU  - Mouhamadou Birame Diop
    AU  - Modou Sarr
    AU  - Mouhamadou Sembene Boye
    AU  - Sérigne Cissé
    AU  - Libasse Diop
    AU  - Allen G. Oliver
    AU  - David Renald
    Y1  - 2022/10/30
    PY  - 2022
    N1  - https://doi.org/10.11648/j.am.20221104.12
    DO  - 10.11648/j.am.20221104.12
    T2  - Advances in Materials
    JF  - Advances in Materials
    JO  - Advances in Materials
    SP  - 85
    EP  - 93
    PB  - Science Publishing Group
    SN  - 2327-252X
    UR  - https://doi.org/10.11648/j.am.20221104.12
    AB  - Two tetrachloridocobaltate (II) hybrid compounds were isolated and structurally characterized by single crystal X-ray crystallography. The compound [(C38H30N8)2•CoCl4] (1), crystallizes in the monoclinic space group P21/c with Z = 4, a = 12.0894(7) Å, b = 15.1839(8) Å, c = 19.8015(11) Å, β = 90.786(2)° and V = 3634.5(3) Å3. Compound [(CH3NH3)2•CoCl4] (2), crystallizes in the monoclinic space group P21/c with Z = 4, a = 7.6385(5) Å, b = 12.6684(8) Å, c = 10.8730(6) Å, β = 96.540(2)° and V = 1045.31(11) Å3. The compound 1 consists of 2,3,5-triphenyltetrazolium cations and tetrachloridocobaltate (II) ions connected through weak C-H•••Cl hydrogen bonds affording a 3D structure. Additional π•••π interactions consolidate the stability and the compactness of the 3D framework. The tetrazolium (C1N1N2N3N4) ring forms dihedral angles of 85.04(11), 49.37(11) and 27.85(11)° with the planes of the benzene rings of the substituent groups while the tetrazolium (C20N5N6N7N8) ring forms dihedral angles of 52.92(11), 47.37(11) and 9.97(11)° with the planes of the benzene rings of the substituent groups. The compound 2 is composed of methylammonium cations and tetrachloridocobaltate (II) dianions connected by extended N-H•••Cl hydrogen bonding patterns giving rise to a 3D structure. The methylammonium cations adopt a general position and are not exceptional. In both structures, the Co centre within the dianion is bonded to four chloride ligands and adopts a distorted tetrahedral geometry. The extensive hydrogen bonding patterns within compound 2 describe R22(4), R34(10), R44(12), R55(14), R46(14), R56(16) and R66(18) rings whereas 1, through the weak C-H•••Cl hydrogen bond patterns, generates mainly R21(4) rings and other hydrogen bonds of D type.
    VL  - 11
    IS  - 4
    ER  - 

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Author Information
  • Inorganic and Analytical Chemistry Laboratory, Department of Chemistry, Faculty of Science and Technology, Cheikh Anta Diop University, Dakar, Senegal

  • Inorganic and Analytical Chemistry Laboratory, Department of Chemistry, Faculty of Science and Technology, Cheikh Anta Diop University, Dakar, Senegal

  • Department of Physic and Chemistry, Faculty of Science and Technology of Education and Training, Cheikh Anta Diop University, Dakar, Senegal

  • Inorganic and Analytical Chemistry Laboratory, Department of Chemistry, Faculty of Science and Technology, Cheikh Anta Diop University, Dakar, Senegal

  • Inorganic and Analytical Chemistry Laboratory, Department of Chemistry, Faculty of Science and Technology, Cheikh Anta Diop University, Dakar, Senegal

  • Department of Chemistry and Biochemistry, University of Notre Dame, Nieuwland, USA

  • Reactivity and Solid State Chemistry Laboratory, University of Picardie, Jules Verne, Amiens, France

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